Gas chromatographic determination of peroxyacetyl nitrate: Two convenient calibration techniques     

Horst Meyrahn  Günter Helas  Peter Warneck 《Journal of Atmospheric Chemistry》1987,5(4):405-415

Two procedures for the calibration of an electron capture detector (ECD) for peroxyacetyl nitrate (PAN) are discussed. One is based on the first-order decay rate of the the PAN mixing ratio in conditioned glass storage vessels. The other method makes use of the photochemical generation of PAN in mixtures of acetone and NO₂ in air. For this purpose a Penray Hg lamp was inserted into a glass vessel filled with 1 atmosphere of air containing 10 ppm NO₂ and 1% acetone. After 3 min of irradiation, the average PAN mixing ratio formed was 8.87±0.25 ppmv as determined in six separate runs.  相似文献   

黄铁矿与沥青铀矿的共生条件及在沥青铀矿形成过程中所起作用的实验研究   总被引：5，自引：0，他引：5  

赵凤民  沈才卿 《铀矿地质》1986,(4)

高价铁与高价铀混合溶液在还原场中形成了共生的黄铁矿与沥青铀矿,该过程必须在弱酸性-中性-碱性介质中进行,其中在弱酸性至中性介质中易形成大的黄铁矿单晶。高价铀溶液流经黄铁矿矿区时,若在高温高压条件下,有新生的黄铁矿或白铁矿与沥青铀矿共生。黄铁矿还原六价铀形成沥青铀矿时,起还原作用的是二价硫。赤铁矿常与沥青铀矿共生,但它们是热液演化过程中不同阶段的产物,赤铁矿形成于体系氧逸度高的氧化环境,沥青铀矿形成于体系氧逸度低的还原环境,赤铁矿形成于沥青铀矿之前。  相似文献   

Pyrolysis of immature Torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryococcus braunii. Mechanism of formation and structure of torbanite     

C. Largeau  S. Derenne  E. Casadevall  A. Kadouri  N. Sellier 《Organic Geochemistry》1986,10(4-6)

Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C₃₁. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role.  相似文献   

Ra法找矿及其在异常评价中的应用     

龚新喜  胡敏知 《华东地质学院学报》1986,(2)

本文介绍带电收集片测定土等粉末样品的 Ra 含量来找 U 矿的方法,称为 Ra 法。此法灵敏度高,操作简便,成本低,可以使用~(210)Po 法曲仪器和铜片,便于推广使用。文中介绍了测 Ra 流程,测定误差和灵敏度.Ra 法在详查和区调阶段的用途。总结了深部盲矿、地表矿化和非矿异常地段上地表的 Ra、Po 和γ异常的特征,指明 Ra 法和 Po 法结合可用于评价异常,提高找深部铀矿的能力。  相似文献   

古风化壳是碳酸盐岩一个重要的储集层(体)类型   总被引：22，自引：0，他引：22       下载免费PDF全文

贾振远  肖玉茹 《地球科学》1995,20(3):283-289

大量含油气区的勘探开发证明，古风化壳是碳酸盐岩一个重要的储集层（体），作者以塔里木盆地下古生界古风化壳储集层（体）为基础，结合鄂尔多斯地区和任丘油田，从地层、岩矿组成、成岩作用、古岩溶、垂向结构、储集性能、测井曲线、地震反射和含油气性诸方面进行了详细研究，大量资料证明，古风化壳是经长期表生成岩作用形成的特有的地质体，其内部具有特有的分带性结构和含油气性，用岩溶并不能代表它的特殊性和整体概念，应黎  相似文献   

川黔湘交境寒武纪层序划分   总被引：7，自引：2，他引：7       下载免费PDF全文

徐世球  段冶 《地球科学》1995,20(5):485-495

根据层序地层学的基本原理和概念，以露头剖面研究为基础将川黔湘交境寒武素划分为１６个三级层序，其中下统含７个中统３个，上统６个，既有Ⅰ型层序又有Ⅱ型层序，具倾斜边缘的盆地中形成的Ⅰ型层序仅发育在早寒武世早期，共２个；具台缘斜坡的盆地中形成的Ⅰ型层序发育在台地形成及发展阶段，即早寒武世后期至晚寒武世早中期，共５个。上述层序的详细研究为海平面升降和加里东早期的构造运动的认识提供了新的基础。  相似文献   

Determination of arsenic(III) for the investigation of the microbial oxidation of arsenic(III) to arsenic(V)     

B. Hambsch  B. Raue  H.-J. Brauch 《洁净——土壤、空气、水》1995,23(4):166-172

Recent evaluations of acute and chronical toxicity of arsenic resulted in a reduction of the standard value for total arsenic from 40 μg/L to 10 μg/L in drinking water which will be valid in Germany after a transition period as from January 1996. Arsenic is well known as substance of deep groundwaters, mainly of geogenic origin and normally found as As(III) or As(V). As(V) is well removable by flocculation and filtration after adding iron salts. As(III), however, has to be oxidized first to As(V). Therefore, it is important for treatment techniques to be able to distinguish between As(III) and As(V). A modified determination of As(III) using flow injection analysis was installed and optimized in order to investigate whether As(III) may be oxidized to As(V) by bacteria in natural waters. The results showed that at 4°C, no As(III)-oxidation was observed within 14 days. At room temperature, however, in the bacteria-containing samples, an As(III)-oxidation was found starting after 3 to 7 days. After 14 days, no As(III) was left over. In contrast, in the sterile samples, no As(III)-oxidation could be observed within 14 days. These results demonstrated that microbial processes influence the oxidation of As(III) to As(V) in natural waters.  相似文献   

Trace analysis of quaternary aminoalcohols as degradation products from softeners in wastewater     

H. Engelhardt  W. Gtzinger  M. Krmer  R. Wintringer 《洁净——土壤、空气、水》1995,23(4):173-179

The sensitive and selective determination of polyalcohols without chromophores or fluorophores in the lower ppb-level is still an analytical task of high interest, especially in the field of environmental investigations. This paper describes a cation-exchange HPLC procedure for the separation and fluorescence detection of two quaternary ammonium compounds with polyalcoholic groups (degradation products of fabric softener) after derivatization with 9-fluorenylmethyl chloroformate (FMOC). Detailed experiments were carried out to determine optimum reaction conditions (pH, reaction time, temperature), linear range, detection limits, and kinetics of the reaction. The HPLC separation on a cation-exchange column includes a gradient program which provides complete separation from neutral compounds also reacting with FMOC and its hydrolysis products formed during the reaction in alkaline medium. High specificity for both investigated ammonium compounds with detection limits in the range of 1 ppb could be achieved.  相似文献   

陕西陶湾群北侧剪切混杂带的确定及其地质意义     

韩志勇  张寿广 《地质论评》1995,41(3):221-228

陕西境内的陶湾群和大片出露的寒牙纪地层之间，发育一套以千枚岩夹白云岩透镜体为主的复杂岩系。这套岩系实际上构成一个剪切混杂带，成为秦岭造山带和华北地台的界线，该带不是一个沉积地层单位，而应视为岩石－构造组合体，带内发育一系列冲断层，在洛南柏峪寺地区，从中可以分出３个构造岩片，其中的白云岩岩块为构造岩块。根据显微，小构造分析及岩性对比，认为冲断层由北向南逆冲，带内至少卷入有晚元古代大庄组，震旦纪罗圈组  相似文献   

龙门山冲断带的隆升和川西前陆盆地的沉降   总被引：69，自引：11，他引：69       下载免费PDF全文

刘树根 Demis.  A 《地质学报》1995,69(3):204-214

通过龙门山区和川西前陆盆地岩石样品的裂变径迹和镜质体反射率的测定和计算机模拟得出：１）松潘－甘孜褶皱带１０Ｍａ以来至少隆升了３－４ｋｍ，隆升速率最低为０．３－０．４ｍｍ／ａ；（２）龙门山逆冲推覆构造带１０Ｍａ以来至少隆升了５－６ｋｍ，隆升速率最低为０．０１６－０．０３２ｍｍ／ａ；（４）川西前陆盆地６０Ｍａ以来降升１－２ｋｍ，降升速率为０．０２８－０．０５ｍｍ／ａ；（５）１０Ｍａ以来北川－映秀－小关  相似文献